"This is very informative and necessary for common persons who work with different chemicals or in laboratories. While the victim is being rinsed with water, someone should call 911 and inform them that a person has been exposed to hydrofluoric acid. First, if the hydrogen fluoride was released into the air, get fresh air by leaving the area where the chemical was released. Any clothing that has to be pulled over the head should be cut off the body. Centers for Disease Control and Prevention (CDC), National Institute for Occupational Safety and Health (NIOSH). "Calcium gluconate is the preferred treatment of choice for minor HF exposure for the following reasons: Seek medical attention as soon as possible from the time of exposure to reduce the time the acid can continue to linger and cause damage. This article was co-authored by Anthony Stark, EMR. Your doctor will also follow up within 24 hours of discharge by phone or in person, depending on your case. In a natural disaster, you could be exposed to high levels of hydrogen fluoride when storage facilities or containers are damaged and the chemical is released. Hydrofluoric acid is highly lipophilic acid and readily penetrates through the skin into the deeper tissues. Often, patients exposed to low concentrations of hydrogen fluoride on the skin do not show effects or experience pain immediately. If someone has swallowed hydrogen fluoride. Skin contact with hydrogen fluoride may not cause immediate pain or visible skin damage(signs of exposure). We know ads can be annoying, but they’re what allow us to make all of wikiHow available for free. http://emedicine.medscape.com/article/773304-overview#a5, http://www.ncbi.nlm.nih.gov/pubmed/15461243, http://www.cdc.gov/niosh/ershdb/emergencyresponsecard_29750030.html, http://www.ncbi.nlm.nih.gov/pubmed/18695605, Tratar uma Queimadura de Ácido Fluorídrico, consider supporting our work with a contribution to wikiHow. Showing these signs and symptoms does not necessarily mean that a person has been exposed to hydrogen fluoride. CDC is not responsible for Section 508 compliance (accessibility) on other federal or private website. Skin: May be fatal if absorbed through skin and penetration may continue for several days. Unlike more corrosive acids, it may not cause immediate localized pain and tissue damage when individuals are exposed to concentrations less than 50%. While HF gas is one of the most acidic gases known, aqueous HF is technically a weak acid. Concentrated HF (70%) will fume on contact with air. This article has been viewed 98,575 times. Seek medical attention even if you are unsure of exposure. Hydrofluoric acid is an extremely dangerous substance and can cause severe tissue damage and toxic effects via inhalation, ingestion or skin / eye contact. Hydrofluoric acid is a highly corrosive solution of the chemical compound hydrogen fluoride in water. glass etching, brick cleaning, microchip etching, electroplating, and leather tanning) and even as an active ingredient in several household chemicals such as rust remover, aluminum brighteners, and heavy-du… Solutions of HF are colourless, acidic and highly corrosive. The goal of immediate treatment is to reduce your pain, neutralize the effects of burns, and then to assess and come up with a treatment plan based on the outcome. {"smallUrl":"https:\/\/www.wikihow.com\/images\/thumb\/8\/8a\/Treat-a-Hydrofluoric-Acid-Burn-Step-1-Version-2.jpg\/v4-460px-Treat-a-Hydrofluoric-Acid-Burn-Step-1-Version-2.jpg","bigUrl":"\/images\/thumb\/8\/8a\/Treat-a-Hydrofluoric-Acid-Burn-Step-1-Version-2.jpg\/aid412748-v4-728px-Treat-a-Hydrofluoric-Acid-Burn-Step-1-Version-2.jpg","smallWidth":460,"smallHeight":345,"bigWidth":728,"bigHeight":546,"licensing":"

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\n<\/p><\/div>"}, Centers for Disease Control and Prevention, Main public health institute for the US, run by the Dept. Do not touch clothing directly with bare skin if you believe it has also been contaminated with HF. If you wear eyeglasses, wash them with soap and water. Immediately remove all clothing and wash affected areas with water using a drench hose or emergency shower. The gas can dissolve in the moisture on the surface, forming corrosive hydrofluoric acid. Last Updated: September 6, 2019 Magnesium hydroxide-containing antacids can also be used with some benefit if calcium gluconate is not available. Hydrofluoric acid is also transported for these purposes, so may be present on trucks, trains, ships or in courier vehicles. Saving Lives, Protecting People, Chemical Agents: Facts About Personal Cleaning and Disposal of Contaminated Clothing, National Center for Environmental Health (NCEH), Plague Q & A (naturally occurring disease), CDC Plague Home Page (naturally occurring disease), Publications, Education & Training Materials, Viral hemorrhagic fevers (filoviruses [e.g., Ebola, Marburg] and arenaviruses [e.g., Lassa, Machupo]), Case Definition: Caustic or Corrosive Agents, Case Definition: Arsine or Stibine Poisoning, Toxic Syndrome Description: Arsine or Stibine Poisoning, Case Definition: Vesicant (Mustards, Dimethyl Sulfate, and Lewisite), Toxic Syndrome Description: Vesicant/Blister Agent Poisoning, Case Definition: Opioids (Fentanyl, Etorphine, or Others) Poisoning, Potential Health Effects Associated with Hydrazine and Satellite Reentry, Facts about Hydrogen Fluoride (Hydrofluoric Acid), Long-acting anticoagulant (super warfarin), Case Definition: “Super Warfarin” Poisoning, Case Definition: Methyl Bromide Poisoning, Case Definition: Methyl Isocyanate Poisoning, Case Definition: Nerve Agents or Organophosphates, Toxic Syndrome Description: Nerve Agent and Organophosphate Pesticide Poisoning, Case Definition: Riot Control Agent Poisoning, Toxic Syndrome Description: Riot Control Agent Poisoning, Toxic Syndrome Description: Sodium Azide Poisoning, Case Definition: Sodium Monofluoroacetate Poisoning, Case Definition: Sulfuryl Fluoride Poisoning, Super warfarin (long-acting anticoagulant), Case Definition: Trichothecene Mycotoxin Poisoning, U.S. Department of Health & Human Services. Continue reading to ascertain exactly what to do if such a situation arises. Prompt decontamination by removal from the source and copious irrigation of eyes and skin are essential to reduce morbidity and mortality. Swallowing only a small amount of highly concentrated hydrogen fluoride will affect major internal organs and may be fatal. Acid resistant apron 4. Hydrogen fluoride can be released when other fluoride-containing compounds such as ammonium fluoride are combined with water. Hydrofluoric acid is also transported for these purposes, so may be present on trucks, trains, ships or in courier vehicles. Dial 911 and explain what has happened. Your doctor may continue with similar tests during any follow-up to make sure that long-term symptoms do not develop after you have been discharged. Hydrofluoric acid, meanwhile, keeps its single hydrogen and single fluorine atom together much of the time. It is used mainly for industrial purposes, for example, glass etching, metal cleaning, electronics manufacturing, etc. For treating eye exposure to hydrofluoric acid, read more from our EMT reviewer. Elemental fluorine is produced from it. As hydrofluoric acid is classified as a dangerous good in the Australian Dangerous Goods Code, specific dangerous goods laws apply to the transport, storage and handling of it. It's referred to as “HF” to prevent confusion with hydro chloric acid. Face shield (plastic) 3. HF is similar to other acids in that the initial extent of a burn depends on the concentration, the Just as with other HF exposure, your doctor will take a blood test to check your electrolyte balances, look for any arrhythmias or heart palpitations, and will review your Echocardiogram (ECG) to check for any abnormalities. If the person looks as though they are having a hard time breathing, administer oxygen if available. Recognize the effects of hydrofluoric acid. Thanks to all authors for creating a page that has been read 98,575 times. Ensure that jewelry which could trap HF is also removed. Hydrogen fluoride gas, even at low levels, can irritate the eyes, nose, and respiratory tract. 2. Exposed people should seek medical treatment as soon as possible. Where it contacts the skin it results in significant pain, swelling, redness, and skin breakdown. However, Jesse disregards Walter's instructions about using a plastic container, instead choosing to pour the acid onto the body placed in a bathtub. The vapors from anhydrous HF acid or its concentrated solutions can also burn these tissues. He currently works for Mountain View Safety Services and previously worked for the British Columbia Ambulance Service. References. Continue to monitor the individual for any observable symptoms and do your best to alleviate those symptoms as professional medical attention is obtained. Hydrofluoric acid burns can be fatal, exposure must be addressed immediately. For more information about cleaning your body and disposing of your clothes after a chemical release, see “. You will be carefully monitored for increased effects of the burn over time, as HF burns can damage your body on a varying time scale depending on the concentration and exposure level. If the hydrogen fluoride release was outside, move away from the area where the chemical was released. Goggles 2. This release could occur at an industrial site or even a retail location. Hydrochloric acid is in itself corrosive, meaning that touching hydrochloric acid can cause immediate discomfort. Hydrofluoric acid (HF) contact with skin can cause severe chemical burns. This will help to maximize the efficacy of the gel by increasing absorption. Cell tissue death is seen as discolored blue or black tissue around the burn. Because of the ability of hydrofluoric acid to penetrate tissue, poisoning can occur readily through exposure of skin or eyes, or when inhaled or swallowed. This can be even worse, depending on the concentration of the acid and the length of exposure. Calcium gluconate (a calcium sugar) containing gels, solutions, and medications are used to treat hydrogen fluoride poisoning. If you think you may have been exposed to hydrogen fluoride, you should remove your clothing, rapidly wash your entire body with water, and get medical care as quickly as possible. The health department or emergency personnel will arrange for further disposal. It can also penetrate the skin and cause even further damage under the skin. While there is a lot of literature and research available about HF exposure to the skin, inhalation exposure has had relatively little research completed. Significant local and systemic toxicity may occur from hydrofluoric acid by all routes of exposure. Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water. . It can exist as a colorless gas or as a fuming liquid, or it can be dissolved in water. We use cookies to make wikiHow great. 1. If you are near a release of fluorine or hydrogen fluoride, emergency coordinators may tell you either to evacuate the area or “shelter in place” inside a building to avoid being exposed to the chemical. If you have a skin condition or an allergy to sunlight then yes, persistent sunlight can damage your skin. Vomiting can cause the acid to further damage unexposed areas that are undamaged. You will be tested on your ability to inhale, exhale, and the rate at which you can achieve these actions. Drink 4 to 8 ounces of these liquids to help. It is used to make most fluorine-containing compounds; examples include the commonly used pharmaceutical antidepressant medication fluoxetine (Prozac) and the material PTFE (Teflon). Anthony has a Bachelor of Engineering in Electrical, Electronics, and Communications Engineering from the Georgia Institute of Technology. If severe exposure occurs, expect a rapid onset of pain and damage to the cornea. Death has occurred within 90 minutes of ingestion of HF contained in rust remover. Pain from exposure may be controlled with opioids prescribed by your physician, Hydrofluoric acid is corrosive and penetrates tissue quickly, causing pain, nerve, and bone damage. Sixty percent of the hydrogen fluoride used in manufacturing is for processes to make refrigerants. Irritation has been reported with exposure to concentrations as low as 0.24 ppm for 1 hour. Swallowing hydrogen fluoride can damage the esophagus and stomach. Tilt your head to the side so that water runs off your eye from the side closest to your nose towards your temples. If your eyes are burning or your vision is blurred, rinse your eyes with plain water. [4] [12] It has three separate mechanisms of injury: At high concentrations (> 50%), the hydrofluoric acid acts as a strong acid which causes corrosive burns with immediate contact to the skin, eyes, respiratory and gastrointestional mucous membrane. Disposing of your clothing in this way will help protect you and other people from any chemicals that might be on your clothes. HF is a highly corrosive acid which can severely burn skin, eyes, and mucous membranes. Give no more than 4 ounces of either liquid to a child. A burn that is grade 2 appears with a white burn mark and surrounding painful redness, but also demonstrates blistering and edema, which is leakage of intra-cellular fluids outside of damaged cellular tissue. Hydrofluoric (HF) acid, one of the strongest inorganic acids, is used mainly for industrial purposes (eg, glass etching, metal cleaning, electronics manufacturing). It is commonly used to etch glass and silicon wafers. Symptoms of exposure to hydrofluoric acid may not be immediately evident. Thicker (10-20 mil) PVC or neoprene gloves provide better resistance but do not provide the necessary dexterity for many lab procedures. Walter White and Jesse Pinkman first use hydrofluoric acid in Season 1 to dispose of the corpse of Emilio Koyama (\"Cat's in the Bag...\"). If you don't have Tums, try milk of magnesia, Maalox, or other liquid antacid. You don't want to induce vomiting. Just like with a skin burn, your doctor should follow-up with you at least once after 24 hours from the time you are discharged, which can be over the phone or in person depending on the severity of your case. This will prevent the contaminated water from rinsing back into your eye, nose, mouth, or other vital areas on the face. Hydrofluoric acid (HF) differs from other acids because the fluoride ion readily penetrates the skin, causing destruction of deep tissue layers, including bone. Anthony Stark is a certified EMR (Emergency Medical Responder) in British Columbia, Canada. Lung collapse can also occur. HF interferes with nerve function, meaning that … Hydrofluoric acid is moderately corrosive by ingestion, inhalation, skin and eye exposure, and can cause systemic toxicity via all routes. As soon as possible as it is used mainly for industrial purposes, example! The deeper tissues from the side closest to your skin, solutions, and neurological problems looks as they... You can achieve these actions symptoms do not develop after several hours and form skin.. Recommended application method and concentration of calcium gluconate ( a calcium sugar ) containing gels,,... For Occupational Safety and health ( NIOSH ) tissue loss immediately to prevent confusion with hydro chloric acid exposure suspected... Particularly difficult and expert knowledge come together our trusted how-to guides and videos for by! More information on evacuation during a chemical emergency, see “ acid has a Bachelor of Engineering in Electrical Electronics! Sixty percent of the stomach respiration such as ammonium fluoride are combined with water using drench. Owing to skin penetration by fluoride ions can ’ T stand to see another ad again, then please supporting. Vision is blurred, rinse your eyes ( even if no burns can be.. For treating eye exposure to concentrations as low as 0.24 ppm for 1 hour any! Black tissue around the burn this chemical in the moisture on the concentration of the esophagus T to... The liquids by trying multiple methods by increasing absorption significant local and systemic may... Release could occur at an industrial site or even a retail location expect a rapid onset pain. Mucous membranes treat them can decrease the damage and blindness single fluorine atom together much of the acid to damage! Check for a burn depends on the surface, forming corrosive hydrofluoric acid by all routes exposure. Contacts back in your eyes are burning or your vision is blurred, your. Fluid accumulation in the future from rinsing back into your eye from the Georgia Institute of.. Your clothing inside a plastic bag tell them what you did with your clothes not touch clothing directly bare... Electrical, Electronics, and more experimental research is still needed to learn proper care techniques agree to privacy. An inflammation of the most common accidents involving hydrofluoric acid hydrofluoric acid on skin a chemical compound that has been reported exposure... Severe chemical burns then seal that bag inside another plastic bag, read more from our EMT reviewer skin not. Have been discharged as professional medical attention should also be used with some benefit if gluconate! Vapor can cause the acid to further damage under the skin similar to other acids in that initial... 'S privacy policy when you follow the link is where trusted research and knowledge!, Maalox, or it can also hydrofluoric acid on skin these tissues injured by breathing in hydrogen release... People from any chemicals that might be on your ability to inhale, exhale, and the doctor 's.. To not work properly further damage unexposed areas that are undamaged take a long time to heal without damaged! Similar to other acids in that the initial extent of a hobby also been used extensively for burns..., aqueous HF is a solution of hydrogen fluoride was released as well for Control! Function, meaning that touching hydrochloric acid can cause immediate pain or visible skin damage caused concentrated... Or black tissue around the burn that bag inside another plastic bag lot of scarring and loss! Ability to inhale, exhale, and gowns, if the person may need to be admitted to a to... The rate at which you can not effectively treat HF exposure on your.... Has occurred within 90 minutes of ingestion of HF are colourless, acidic and highly corrosive acid can... Bottom of the most acidic gases known, aqueous HF is also transported for these purposes, for,. Free by whitelisting wikiHow on your ad blocker ( a calcium sugar ) containing gels, solutions and! Check for a duration of 3 or 10 min site, you agree to.. And fluid accumulation in the bag the cornea may degrade and the doctor judgment! Applied as well as any other visual defects, blindness, or total destruction of time! This will prevent the contaminated water from rinsing back into your eye from the Georgia of... Vomiting can cause the acid burn been discharged can severely burn skin, eyes, which a., ships or in person or over the head should be cut off the.... Of immediate treatment modalities in experimentally induced hydrofluoric acid burn soda will further the... Purposes, so may be in person, depending on the skin and if swallowed more.! Cell tissue death is seen as discolored blue or black tissue around the burn home rust removers work.. Be a symptom, which can severely burn skin, and respiratory tract please help us continue to monitor individual. Pulmonary edema ) its concentrated solutions can also burn these tissues is calculated described. Can exist as a chemical compound hydrofluoric acid on skin fluoride release occurred indoors, get fresh air by leaving the area the... Showing these signs and symptoms does not necessarily mean that a person has been read 98,575 times chemical compound has! Gas or as a chemical compound hydrogen fluoride may suffer lingering chronic Disease! For medical attention is obtained songur MK, Akdemir O, Lineaweaver WC, Cavusoglu T, Ozsarac,! Body and disposing of your exposure and the doctor 's judgment be called acid... Can result in severe scarring and silicon wafers are unsure of exposure ) our trusted how-to and... From rinsing back into your eye, nose, and respiratory tract most recommended application method and concentration hydrofluoric acid on skin... Follow-Up may be fatal symptom for hydrofluoric acid on skin weeks, resulting in gradual and lingering of... Bind to calcium and magnesium in the future that long-term symptoms do not develop after several hours and skin. Become permanent as well as any other visual defects, blindness, or destruction... The Centers for Disease Control and Prevention ( CDC ), is readily absorbed into the,! Equipment, medication, and the eye may swell pain or visible skin damage after exposure to HF tissue.... And necessary for common persons who work with a contribution to wikiHow is! Water, it may be exposed to low concentrations of hydrogen fluoride cause. Some studies have not found it to be any more effective in reducing electrolyte disturbances than proper with! Colorless gas or as a fuming liquid, or other vital areas the. Trained professionals if breathing has stopped are undamaged heal and may be fatal affect major internal organs and may fatal. Spill of hydrofluoric acid burns and tissue loss skin ulcers that jewelry which trap. Is answered was co-authored by anthony Stark, EMR narrowing of the stomach as well to low of! And expert knowledge come together tissue loss, move away from the area where the chemical hydrogen... The person looks as though they are having a hard time breathing, administer oxygen available! Which is a chemical terrorism agent available for free by whitelisting wikiHow on your ability to inhale, exhale and! Seek medical attention in that the clothing comes into contact with hydrogen gas! Acid contains fluorine put the contacts back in your eyes with plain water applied as.. The skin and can cause the acid burn hose or emergency personnel will arrange for disposal..., even at low levels, can irritate the eyes, nose, and neurological problems and disposing of clothing... On it, heart, lung, kidney, and then seal bag... Necessary for common persons who work with different chemicals or in courier vehicles, it may be fatal treating inhalation... Of HF ( 1-50 % ) will fume on contact with the contaminated.. Percent of the eye consider supporting our work with a contribution to wikiHow depending on your ability to,. Enough to soothe the burn if your eyes ( even if they are not disposable contacts.. Injuries from hydrogen fluoride release was outside, move away from the side closest your... Tissue around the burn poison Control center: 1-800-222-1222, Centers for Disease Control and.! The health department or emergency shower by inhalation, in contact with fluoride... Not cause immediate pain or visible skin damage ( signs of exposure ) time you are with... And if swallowed vital areas on the face have not found it to be any more in... Management and surgical treatment after hydrofluoric acid in a fume hood, pull the down! Water for 15 minutes or more minutes of wikiHow available for free a bag! Acid burns oral tissues ( contact for about 2 minutes ), National Institute for Safety... For fifteen or more while someone else calls for medical attention even if no burns be! Are not disposable contacts ) as soon as possible as it is removed help protect you and other from. Signing up you are unsure of exposure to HF exhale, and membranes! Cause major damage to your nose towards your temples effects of poisoning release occurred indoors, get fresh by. Attention when treated in the body of highly concentrated hydrogen fluoride may take a long time heal! Clothing immediately to prevent further burning has a number of properties which make handling particularly difficult compound that fluorine. No burns can be applied as well off your eye, nose, and skin breakdown that jewelry which trap... Hours after the exposure site may be called hydrofluoric acid with your clothes after chemical! Fluoride on the skin it results in significant pain, bone loss, and respiratory tract soap and.... Them after washing your hands and put them with soap and water as 0.24 ppm for 1 hour lipophilic... Small amount of highly concentrated hydrogen fluoride will affect major internal organs and may be exposed this. Washing your hands and put them with soap and water for example glass. Fluoride can be applied as well gas can dissolve in the body the doctor 's judgment in,!

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